Clinopyroxene composition as a method of identification of the magmatic affinities of paleo-volcanic series

Uranium contents and²³⁴U/²³⁸U activity ratios have been determined for groundwaters from the Lincolnshire Limestone artesian aquifer in eastern England. Changes in the quantitative and isotopic chemistry of the dissolved uranium are explained in terms of a mixing model involving the rapidly moving fissure water and much older water stored in the pore system of this oolitic limestone. The western part of the aquifer, closest to recharge, is dominated by oxidising groundwaters which then enter a reducing zone towards the east, where there is an abrupt decrease in Eh and the chlorinity of the groundwaters begins to increase. Uranium contents in the oxidising zone range from 0.7 to 3.4 μg kg^?1 and²³⁴U/²³⁸U activity ratio of this dissolved uranium is close to unity, the equilibrium value. The uranium content decreases abruptly when the grounwaaters enter the reducing zone, averaging 0.04 μg kg^?1 east of the oxidation/reduction barrier. Simultaneously with the decrease in uranium content, there is an increase in²³⁴U/²³⁸U activity ratio and this ratio increases to a maximum within 7 km of the oxidation/reduction barrier. This increase in activity ratio is attributed to enhanced²³⁴U solution due to²³⁴Th recoil from uraniferous fissure surfaces east of the oxidising zone. The activity ratio of dissolved uranium in the ancient pore waters could in principle reach high values due to²³⁴Th recoil from the oolith surfaces. However, the activity ratio actually declines further east and this can only be explained as a consequence of mixing with pore waters in which the uranium activity ratio is closer to equilibrium.²³⁴Th recoil from the oolith surfaces has probably been inhibited by sealing of the uranium-bearing surfaces in the process of oolith cementation.     

Social Applications of Geographical Information Systems: technical tools for social innovation

ABSTRACT

The establishment of the National Key Centre for Social Applications of Geographical Information Systems (GIS) in 1995, under the directorship of Professor Graeme Hugo, was a turning point in the use of GIS in Australia. The field of GIS, previously dominated by environmental applications, now broadened its focus to include populations, services and the interactions between people and the environment. Social applications of GIS offered a unique opportunity to make service planning, reporting, funding allocations and research both smarter and fairer. Geography and geographic relationships as implemented in GIS became the integrating platform for social spatial information, invigorating social research, planning and policy. A key strength of this approach, recognised by Professor Hugo, was the ability to ‘put people back into the planning process’. Further to being an integrating platform, GIS also offered the ability to generate new information and knowledge, which could facilitate evidence-based decision making. This paper focuses in particular on providing a written record of the development of the Accessibility/Remoteness Index of Australia (ARIA) suite of spatial accessibility indices. The lasting legacy and continued relevance of this work in social applications of GIS is also reviewed in this paper, with reference to key examples of how social research and planning in Australia have been made both smarter and fairer through the contributions of Professor Hugo and his team.     

Barium and strontium uptake into larval protoconchs and statoliths of the marine neogastropod Kelletia kelletii

The trace elemental composition of calcified larval hard parts may serve as useful tags of natal origin for invertebrate population studies. We examine whether the trace metal barium (Ba) deposits into the calcium carbonate matrix of molluscan larval statolith and protoconch in proportion to seawater Ba concentration at two temperatures (11.5 and 17°C). We also examine strontium (Sr) uptake as a function of temperature. Using encapsulated larvae of the marine gastropod, Kelletia kelletii, reared in the laboratory under controlled conditions, we demonstrate a significant inverse effect of temperature and a positive effect of seawater Ba/Ca ratio on Ba incorporation into larval carbonates. Ba/Ca partition coefficients (D_Ba) in protoconch were 1.13 at 11.4°C and 0.88 at 17.1°C, while D_Ba in larval statolith measured 1.58 at 11.4°C and 1.29 at 17.1°C. Strontium incorporation into statoliths is also inversely affected by temperature, but there was a significant positive effect of temperature on Sr incorporation into protoconch. These data suggest larval statoliths and protoconchs can meaningfully record variation in seawater physical and chemical properties, and, hence, have potential as natural tags of natal origin.     

Living on the Edge: Increasing Patch Size Enhances the Resilience and Community Development of a Restored Salt Marsh

Foundation species regulate communities by reducing environmental stress and providing habitat for other species. Successful restoration of biogenic habitats often depends on restoring foundation species at appropriate spatial scales within a suitable range of environmental conditions. An improved understanding of the relationship between restoration scale and environmental conditions has the potential to improve restoration outcomes for many biogenic habitats. Here, we identified and tested whether inundation/exposure stress and spatial scale (patch size) can interactively determine (1) survival and growth of a foundation species, Spartina alterniflora and (2) recruitment of supported fauna. We planted S. alterniflora and artificial mimics in large and small patches at elevations above and below local mean sea level (LMSL) and monitored plant survivorship and production, as well as faunal recruitment. In the first growing season, S. alterniflora plant survivorship and stem densities were greater above LMSL than below LMSL regardless of patch size, while stem height was greatest in small patches below LMSL. By the third growing season, S. alterniflora patch expansion was greater above LMSL than below LMSL, while stem densities were higher in large patches than small patches, regardless of location relative to LMSL. Unlike S. alterniflora, which was more productive above LMSL, sessile marine biota recruitment to mimic plants was higher in patches below LMSL than above LMSL. Our results highlight an ecological tradeoff at ~LMSL between foundation species restoration and faunal recruitment. Increasing patch size as inundation increases may offset this tradeoff and enhance resilience of restored marshes to sea-level rise.     

Deposition and provenance of the Early Pleistocene Siliceous Member in Westbury Cave,Somerset, England

The Early Pleistocene is an important interval in the Quaternary period as a time not only of climatic and environmental change, but also of key events in human evolution. However, knowledge of this period in northwest Europe is hampered by the limited extent of deposits of this age. Westbury Cave in the Mendip Hills of Somerset preserves an understudied example of fossil-bearing Early Pleistocene sediments, with rare potential to inform our understanding of British Early Pleistocene stratigraphy and landscape evolution outside the East Anglian Crag Basin. This study identifies the processes responsible for deposition of the Early Pleistocene Siliceous Member in Westbury Cave, thereby aiding taphonomic and palaeoenvironmental interpretations of associated fossil assemblages. New excavations revealed over ten metres of Siliceous Member stratigraphy, dominated by fine-grained silts/clays with interbedded sands and gravels, interpreted as being deposited within a subterranean lake or flooded conduit with fluvial input. All sediments sampled were reversely magnetised and are assigned to the Matuyama Reversed Chron. Lithological analysis of gravel clasts revealed variable components of durable non-local and non-durable local clasts. Gravels containing the latter are interpreted as distal talus slope deposits, and those lacking non-durable lithologies as stream or flood deposits. However, it remains unclear from available data whether apparently non-local clasts were sourced from long distance or stem from a more local, now denuded catchment. Siliceous Member bio- and magnetostratigraphy suggest that deposition occurred late in the Early Pleistocene, a period apparently otherwise unrepresented in the UK.     

Iron oxyhydroxide coating of pyrite for acid mine drainage control

When pyrite oxidizes at near neutral pH in the presence of sufficient alkalinity, Fe oxyhydroxide coatings develop on the surface. As these coatings grow thicker and denser they block oxidant transport from the solution to the pyrite surface and reduce the rate of pyrite oxidation. The authors’ measurements of pyrite oxidation rates in a NaHCO₃ solution show that the coating grows in two stages. In the first stage Fe oxyhydroxide colloids form and then attach to the pyrite surface to produce a slight reduction in oxidant transport. In the second stage interstitial precipitation of Fe oxyhydroxide material between the colloidal particles reduces the oxidant’s diffusion coefficient by more than five orders of magnitude. This causes the pyrite oxidation rate to decline as the square root of time. The kinetic predominance diagram, which compares the rates of Fe transformation reactions, shows that when pyrite oxidation releases Fe quickly enough for the total Fe concentration to rise to about 10⁻⁸ m, ferrihydrite forms but lower rates of Fe release will not produce coatings. Extrapolation of the results to longer times predicts that pyrite-bearing materials need to be treated with an extra source of alkalinity for several decades to produce coatings that are thick enough to be sustained by alkalinity levels typical of groundwater. However, once the coatings develop no additional treatment is needed and further pyrite oxidation simply causes the coating to grow thicker and denser until the entire pyrite grain is pseudomorphically replaced by goethite.     

Recent climate variability and its impacts on soybean yields in Southern Brazil

Recent climate variability in rainfall, temperatures (maximum and minimum), and the diurnal temperature range is studied with emphasis on its influence over soybean yields in southern Brazil, during 1969 to 2002. The results showed that the soybean (Glycine max L. Merril) yields are more affected by changes in temperature during summer, while changes in rainfall are more important during the beginning of plantation and at its peak of development. Furthermore, soybean yields in Paraná are more sensitive to rainfall variations, while soybean yields in the Rio Grande do Sul are more sensitive to variations in temperature. Effects of interannual climatic variability on soybean yields are evaluated through three agro-meteorological models: additive Stewart, multiplicative Rao, and multiplicative Jensen. The Jensen model is able to reproduce the interannual behavior of soybean yield reasonably well.